KEGG   COMPOUND: C12000
Entry
C12000                      Compound                               
Name
Tylactone;
Protylonolide
Formula
C23H38O5
Exact mass
394.2719
Mol weight
394.5448
Structure
Sequence
0 Mtk  1 Mtd  2 Mtd  3 Man  4 Mte  5 Etk  6 Mtk  7 Man
  Gene
0-2 tylG [UP:O33954]; 3 tylG [UP:O33955]; 4-5 tylG [UP:O33956];
6 tylG [UP:O33957]; 7 tylG [UP:O33958]
  Organism
Streptomyces fradiae
  Type
PK
Reaction
R06448 R06450
Pathway
map00522  Biosynthesis of 12-, 14- and 16-membered macrolides
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
Module
M00773  Tylosin biosynthesis, methylmalonyl-CoA + malonyl-CoA => tylactone => tylosin
Enzyme
2.4.1.316
Brite
Lipids [BR:br08002]
 PK  Polyketides
  PK04 Macrolides and lactone polyketides
   C12000  Tylactone
Other DBs
CAS: 74758-60-4
PubChem: 14161
ChEBI: 29700
3DMET: B04406
NIKKAJI: J128.611K
LinkDB
KCF data

ATOM        28
            1   C1y C    29.6584  -22.1061
            2   C1y C    29.6521  -20.6898
            3   C1y C    28.4392  -22.8238
            4   C1x C    28.4200  -19.9977
            5   C1b C    30.8397  -19.9912
            6   C1y C    28.4455  -24.2399
            7   C1a C    27.2390  -22.1442
            8   C1y C    28.4200  -18.6004
            9   C1x C    27.2135  -24.9511
            10  O1a O    29.6459  -24.9321
            11  C5x C    27.2071  -17.9145
            12  C1a C    29.6140  -17.9083
            13  C7x C    25.9623  -24.2590
            14  C2x C    26.0131  -18.6004
            15  O5x O    27.2071  -16.5451
            16  O7x O    24.7050  -24.9449
            17  O6a O    25.9623  -22.8809
            18  C2x C    26.0131  -19.9977
            19  C1y C    23.4729  -24.2017
            20  C2y C    24.7939  -20.6898
            21  C1y C    23.4539  -22.7411
            22  C1b C    22.2599  -24.8622
            23  C2x C    24.7748  -22.0869
            24  C1a C    23.6062  -19.9850
            25  C1a C    22.3424  -22.0490
            26  O1a O    30.8896  -22.8063
            27  C1a C    32.0384  -20.6705
            28  C1a C    22.2255  -26.2429
BOND        28
            1     2   4 1
            2     2   5 1 #Down
            3     3   6 1
            4     3   7 1 #Down
            5     4   8 1
            6     6   9 1
            7     6  10 1 #Down
            8     8  11 1
            9     8  12 1 #Down
            10    9  13 1
            11   11  14 1
            12   11  15 2
            13   13  16 1
            14   13  17 2
            15   14  18 2
            16   16  19 1
            17   18  20 1
            18   19  21 1
            19   19  22 1 #Down
            20   20  23 2
            21   20  24 1
            22   21  25 1 #Up
            23   21  23 1
            24    1  26 1 #Down
            25    1   2 1
            26    5  27 1
            27    1   3 1
            28   22  28 1

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