KEGG ENZYME: 2.5.1.28

ENZYME: 2.5.1.28

Entry

EC 2.5.1.28                 Enzyme

Name

dimethylallylcistransferase;
neryl-diphosphate synthase;
dimethylallyl-diphosphate:isopentenyl-diphosphate dimethylallylcistransferase

Class

Transferases;
Transferring alkyl or aryl groups, other than methyl groups;
Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)

Sysname

prenyl-diphosphate:3-methyl-but-3-en-1-yl-diphosphate prenylcistransferase

Reaction(IUBMB)

prenyl diphosphate + 3-methyl-but-3-en-1-yl diphosphate = diphosphate + neryl diphosphate [RN:R01659]

Reaction(KEGG)

R01659

Substrate

prenyl diphosphate [CPD:C00235];
3-methyl-but-3-en-1-yl diphosphate

Product

diphosphate [CPD:C00013];
neryl diphosphate [CPD:C02569]

Comment

This enzyme will not use larger prenyl diphosphates as efficient donors.

History

EC 2.5.1.28 created 1984

Orthology

K18114

dimethylallylcistransferase

Genes

SLY:	100316884(CPT1)

SDUL:

129890341

Reference

Authors

Banthorpe, D.V., Bucknall, G.A., Doonan, H.J., Doonan, S. and Rowan, M.G.

Title

Biosynthesis of geraniol and nerol in cell-free extracts of Tanacetum vulgare.

Journal

Phytochemistry 15:91-100 (1976)

Reference

2 [PMID:4303098]

Authors

Beytia E, Valenzuela P, Cori O

Title

Terpene biosynthesis: formation of nerol, geraniol, and other prenols by an enzyme system from Pinus radiata seedlings.

Journal

Arch Biochem Biophys 129:346-56 (1969)
DOI:10.1016/0003-9861(69)90185-4

Other DBs

ExplorEnz - The Enzyme Database:

2.5.1.28

IUBMB Enzyme Nomenclature:

2.5.1.28

ExPASy - ENZYME nomenclature database:

2.5.1.28

BRENDA, the Enzyme Database:

2.5.1.28

CAS:

9032-79-5

LinkDB

DBGET integrated database retrieval system