Entry |
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Name |
(+)-corvol ether B synthase
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Class |
Lyases;
Carbon-oxygen lyases;
Acting on phosphates
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Sysname |
(2E,6E)-farnesyl-diphosphate diphosphate-lyase [cyclizing, (+)-corvol ether B-forming]
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Reaction(IUBMB) |
(2E,6E)-farnesyl diphosphate + H2O = (+)-corvol ether B + diphosphate [RN: R11828]
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Reaction(KEGG) |
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Substrate |
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Product |
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Comment |
The enzyme, which forms the sesquiterpene (+)-corvol ether B, has been reported from the bacterium Kitasatospora setae.
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History |
EC 4.2.3.163 created 2017
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Orthology |
K23023 | (+)-corvol ether B/A synthase |
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Genes |
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Reference |
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Authors |
Rabe P, Pahirulzaman KA, Dickschat JS |
Title |
Structures and Biosynthesis of Corvol Ethers--Sesquiterpenes from the Actinomycete Kitasatospora setae. |
Journal |
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Sequence |
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Reference |
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Authors |
Rabe P, Janusko A, Goldfuss B, Dickschat JS |
Title |
Experimental and Theoretical Studies on Corvol Ether Biosynthesis. |
Journal |
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Sequence |
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Reference |
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Authors |
Rinkel J, Rabe P, Garbeva P, Dickschat JS |
Title |
Lessons from 1,3-Hydride Shifts in Sesquiterpene Cyclizations. |
Journal |
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Sequence |
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Other DBs |
ExPASy - ENZYME nomenclature database: | 4.2.3.163 |
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LinkDB |
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