KEGG   REACTION: R02231
Entry
R02231                      Reaction                               
Name
cyclohexanone,NADPH:oxygen oxidoreductase (6-hydroxylating 1,2-lactonizing)
Definition
Cyclohexanone + Oxygen + NADPH + H+ <=> epsilon-Caprolactone + NADP+ + H2O
Equation
C00414 + C00007 + C00005 + C00080 <=> C01880 + C00006 + C00001
Reaction class
RC00001  C00005_C00006
RC00662  C00414_C01880
Enzyme
1.14.13.22
Pathway
rn00930  Caprolactam degradation
rn01120  Microbial metabolism in diverse environments
rn01220  Degradation of aromatic compounds
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.22
     R02231  Cyclohexanone + Oxygen + NADPH + H+ <=> epsilon-Caprolactone + NADP+ + H2O
Orthology
K03379  cyclohexanone monooxygenase [EC:1.14.13.22]
Other DBs
RHEA: 24071
LinkDB

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