KEGG   REACTION: R04700
Entry
R04700                      Reaction                               
Name
(S)-cis-N-methylstylopine,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (14-hydroxylating)
Definition
(S)-cis-N-Methylstylopine + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Protopine + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C06163 + C03024 + C00007 <=> C05189 + C03161 + C00001
Reaction class
RC01007  C05189_C06163
Enzyme
1.14.14.97
Pathway
rn00950  Isoquinoline alkaloid biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00945  Sanguinarine biosynthesis, (S)-reticuline => sanguinarine
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.97
     R04700  (S)-cis-N-Methylstylopine + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Protopine + [Oxidized NADPH---hemoprotein reductase] + H2O
Orthology
K21692  methyltetrahydroprotoberberine 14-monooxygenase [EC:1.14.14.97]
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