KEGG   REACTION: R06463
Entry
R06463                      Reaction                               
Name
10-deoxymethymycin,reduced ferredoxin:oxygen oxidoreductase (methymycin-forming)
Definition
10-Deoxymethymycin + 2 Reduced ferredoxin + Oxygen + 2 H+ <=> Methymycin + 2 Oxidized ferredoxin + H2O
Equation
C11994 + 2 C00138 + C00007 + 2 C00080 <=> C11996 + 2 C00139 + C00001
Comment
CYP107L1
Reaction class
RC01526  C11994_C11996
Enzyme
1.14.15.33
Pathway
rn00522  Biosynthesis of 12-, 14- and 16-membered macrolides
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00776  Pikromycin/methymycin biosynthesis, methylmalonyl-CoA + malonyl-CoA => narbonolide/10-deoxymethynolide => pikromycin/methymycin
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.33
     R06463  10-Deoxymethymycin + 2 Reduced ferredoxin + Oxygen + 2 H+ <=> Methymycin + 2 Oxidized ferredoxin + H2O
Orthology
K16006  pikromycin synthase [EC:1.14.15.33]
Other DBs
RHEA: 40542
LinkDB

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