KEGG   REACTION: R08623
Entry
R08623                      Reaction                               
Name
acetyl-CoA:5-methylthio-2-oxopentanoate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
2-Oxo-5-methylthiopentanoic acid + Acetyl-CoA + H2O <=> 2-(3'-Methylthio)propylmalic acid + CoA
Equation
C17211 + C00024 + C00001 <=> C17214 + C00010
Reaction class
RC00004  C00010_C00024
RC00067  C17211_C17214
Enzyme
2.3.3.17
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.3  Acyl groups converted into alkyl groups on transfer
    2.3.3.17
     R08623  2-Oxo-5-methylthiopentanoic acid + Acetyl-CoA + H2O <=> 2-(3'-Methylthio)propylmalic acid + CoA
Orthology
K15741  methylthioalkylmalate synthase 1 [EC:2.3.3.17]
K15742  methylthioalkylmalate synthase 3 [EC:2.3.3.17]
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