KEGG   REACTION: R08664
Entry
R08664                      Reaction                               
Name
L-leucine,NADPH:oxygen oxidoreductase (N-hydroxylating, decarboxylating)
Definition
L-Leucine + 2 Oxygen + 2 NADPH + 2 H+ <=> 3-Methylbutyraldehyde oxime + 3 H2O + 2 NADP+ + CO2
Equation
C00123 + 2 C00007 + 2 C00005 + 2 C00080 <=> C17255 + 3 C00001 + 2 C00006 + C00011
Comment
multi-step reaction (similar to R10671, R00730+R04460+R07190)
Reaction class
RC00001  C00005_C00006
RC02295  C00123_C17255
Enzyme
1.14.13.-
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.-
     R08664  L-Leucine + 2 Oxygen + 2 NADPH + 2 H+ <=> 3-Methylbutyraldehyde oxime + 3 H2O + 2 NADP+ + CO2
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