KEGG   REACTION: R08665
Entry
R08665                      Reaction                               
Name
homomethionine,[NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
Homomethionine + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> 4-Methylthiobutanaldoxime + 2 [Oxidized NADPH---hemoprotein reductase] + CO2 + 3 H2O
Equation
C17213 + 2 C03024 + 2 C00007 <=> C17241 + 2 C03161 + C00011 + 3 C00001
Comment
multi-step reaction (similar to R10671, R00730+R04460+R07190)
Reaction class
RC02295  C17213_C17241
Enzyme
1.14.14.42
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.42
     R08665  Homomethionine + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> 4-Methylthiobutanaldoxime + 2 [Oxidized NADPH---hemoprotein reductase] + CO2 + 3 H2O
IUBMB reaction hierarchy [BR:br08202]
 1. Oxidoreductase reactions
  1.14.14.42
   R11646  L-Polyhomomethionine <=> omega-(Methylthio)-(E)-alkanal oxime
    R08665  Homomethionine <=> 4-Methylthiobutanaldoxime
Orthology
K12154  homomethionine N-monooxygenase [EC:1.14.14.42]
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