KEGG   REACTION: R08675
Entry
R08675                      Reaction                               
Name
hexahomomethionine,[NADPH---hemoprotein reductase]:oxygen oxidoreductase
Definition
Hexahomomethionine + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> 9-Methylthiononanaldoxime + 2 [Oxidized NADPH---hemoprotein reductase] + CO2 + 3 H2O
Equation
C17233 + 2 C03024 + 2 C00007 <=> C17253 + 2 C03161 + C00011 + 3 C00001
Comment
multi-step reaction (similar to R10671, R00730+R04460+R07190)
Reaction class
RC02295  C17233_C17253
Enzyme
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.42
     R08675  Hexahomomethionine + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> 9-Methylthiononanaldoxime + 2 [Oxidized NADPH---hemoprotein reductase] + CO2 + 3 H2O
IUBMB reaction hierarchy [BR:br08202]
 1. Oxidoreductase reactions
  1.14.14.42
   R11646  L-Polyhomomethionine <=> omega-(Methylthio)-(E)-alkanal oxime
    R08675  Hexahomomethionine <=> 9-Methylthiononanaldoxime
Orthology
K12154  homomethionine N-monooxygenase [EC:1.14.14.42]
K12155  homomethionine N-monooxygenase [EC:1.14.14.42]
Other DBs
RHEA: 33298
LinkDB

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