KEGG   REACTION: R08853
Entry
R08853                      Reaction                               
Name
(+)-epi-isozizaene,reduced-ferredoxin:oxygen oxidoreductase (5R-hydroxylating)
Definition
(+)-epi-Isozizaene + 2 Reduced [2Fe-2S] ferredoxin + 2 H+ + Oxygen <=> (5R)-Albaflavenol + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Equation
C16269 + 2 C22150 + 2 C00080 + C00007 <=> C17955 + 2 C22151 + C00001
Comment
the first step of two-step reaction (see R10072, R08853+R08854)
(S)-form (see R08851+R08852)
Reaction class
RC00723  C16269_C17955
Enzyme
1.14.15.39
Pathway
rn00909  Sesquiterpenoid and triterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.39
     R08853  (+)-epi-Isozizaene + 2 Reduced [2Fe-2S] ferredoxin + 2 H+ + Oxygen <=> (5R)-Albaflavenol + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Orthology
K12645  epi-isozizaene 5-monooxygenase / beta-farnesene synthase [EC:1.14.15.39 4.2.3.47]
Other DBs
RHEA: 25987
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