KEGG   REACTION: R08870
Entry
R08870                      Reaction                               
Name
acetyl-CoA:phosphinopyruvate C-acetyltransferase (thioester-hydrolysing, carboxymethyl forming)
Definition
3-(Hydrohydroxyphosphoryl)pyruvate + Acetyl-CoA + H2O <=> 2-Phosphinomethylmalate + CoA
Equation
C06368 + C00024 + C00001 <=> C17947 + C00010
Comment
2-phosphinomethylmalic acid synthase
Reaction class
RC00004  C00010_C00024
RC00067  C06368_C17947
Enzyme
2.3.3.18
Pathway
rn00440  Phosphonate and phosphinate metabolism
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.3  Acyl groups converted into alkyl groups on transfer
    2.3.3.18
     R08870  3-(Hydrohydroxyphosphoryl)pyruvate + Acetyl-CoA + H2O <=> 2-Phosphinomethylmalate + CoA
Orthology
K12910  2-phosphinomethylmalate synthase [EC:2.3.3.18]
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