KEGG   REACTION: R08923
Entry
R08923                      Reaction                               
Name
(+)-pulegone,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (9-hydroxylating)
Definition
Pulegone + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (+)-Menthofuran + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C09893 + C03024 + C00007 <=> C18025 + C03161 + 2 C00001
Comment
multi-step reaction (9-hydroxylation, cyclization and dehydration)
Reaction class
RC02978  C09893_C18025
Enzyme
1.14.14.143
Pathway
rn00902  Monoterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.143
     R08923  Pulegone + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (+)-Menthofuran + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Orthology
K15093  (+)-menthofuran synthase [EC:1.14.14.143]
Other DBs
RHEA: 25661
LinkDB

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