REACTION: R08935
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Entry
R08935 Reaction
Name
dTDP-6-deoxy-L-mannose:NADP+ 4-oxidoreductase (3,5-epimerizing)
Definition
dTDP-L-rhamnose + NADP+ <=> dTDP-4-oxo-6-deoxy-D-glucose + NADPH + H+
Equation
C03319
+
C00006
<=>
C11907
+
C00005
+
C00080
Comment
two-step reaction (see
R06514+R02777
)
Reaction class
RC00001
C00005_C00006
RC01014
C03319_C11907
Enzyme
1.1.1.-
Pathway
rn00523
Polyketide sugar unit biosynthesis
rn01110
Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:
br08201
]
1. Oxidoreductase reactions
1.1 Acting on the CH-OH group of donors
1.1.1 With NAD+ or NADP+ as acceptor
1.1.1.-
R08935 dTDP-L-rhamnose + NADP+ <=> dTDP-4-oxo-6-deoxy-D-glucose + NADPH + H+
BRITE hierarchy
Orthology
K12451
3,5-epimerase/4-reductase [EC:5.1.3.- 1.1.1.-]
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