KEGG   REACTION: R09234
Entry
R09234                      Reaction                               
Name
4-methyl-5-nitrocatechol,NADPH:oxygen 5-oxidoreductase (5-hydroxylating, nitrite-forming)
Definition
4-Methyl-5-nitrocatechol + NADPH + Oxygen + H+ <=> 2-Hydroxy-5-methylquinone + NADP+ + Nitrite + H2O
Equation
C18315 + C00005 + C00007 + C00080 <=> C18316 + C00006 + C00088 + C00001
Comment
NADH (see R11150)
Reaction class
RC00001  C00005_C00006
RC03020  C18315_C18316
Enzyme
1.14.13.210
Pathway
rn00633  Nitrotoluene degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.210
     R09234  4-Methyl-5-nitrocatechol + NADPH + Oxygen + H+ <=> 2-Hydroxy-5-methylquinone + NADP+ + Nitrite + H2O
Orthology
K21683  4-methyl-5-nitrocatechol 5-monooxygenase [EC:1.14.13.210]
Other DBs
RHEA: 48015
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