KEGG   REACTION: R09272
Entry
R09272                      Reaction                               
Name
3-O-methylgallate:oxygen 3,4-oxidoreductase (decyclizing)
Definition
3-O-Methylgallate + Oxygen <=> 4-Carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate
Equation
C05616 + C00007 <=> C18345
Comment
3-O-methylgallate 3,4-dioxygenase, desZ
Reaction class
RC01369  C05616_C18345
Enzyme
1.13.11.8       1.13.11.-
Pathway
rn00627  Aminobenzoate degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.13  Acting on single donors with incorporation of molecular oxygen (oxygenases)
   1.13.11  With incorporation of two atoms of oxygen
    1.13.11.8
     R09272  3-O-Methylgallate + Oxygen <=> 4-Carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate
    1.13.11.-
     R09272  3-O-Methylgallate + Oxygen <=> 4-Carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate
Orthology
K04100  protocatechuate 4,5-dioxygenase, alpha chain [EC:1.13.11.8]
K04101  protocatechuate 4,5-dioxygenase, beta chain [EC:1.13.11.8]
K15065  3-O-methylgallate 3,4-dioxygenase [EC:1.13.11.-]
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