KEGG   REACTION: R09353
Entry
R09353                      Reaction                               
Name
premithramycin-B,NADPH:oxygen oxidoreductase
Definition
Premithramycin B + NADPH + H+ + Oxygen <=> Mithramycin DK + NADP+ + CO2
Equation
C12388 + C00005 + C00080 + C00007 <=> C18711 + C00006 + C00011
Comment
Baeyer-Villiger monooxygenase
Reaction class
RC00001  C00005_C00006
RC02490  C12388_C18711
Enzyme
1.14.13.-
Pathway
rn01057  Biosynthesis of type II polyketide products
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00782  Mithramycin biosynthesis, 4-demethylpremithramycinone => mithramycin
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.-
     R09353  Premithramycin B + NADPH + H+ + Oxygen <=> Mithramycin DK + NADP+ + CO2
Orthology
K15966  monooxygenase [EC:1.14.13.-]
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