KEGG   REACTION: R09923
Entry
R09923                      Reaction                               
Name
(-)-linalool,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (8-hydroxylating)
Definition
(-)-Linalool + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (6E)-8-Hydroxylinalool + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C11388 + C03024 + C00007 <=> C04433 + C03161 + C00001
Reaction class
RC01137  C04433_C11388
Enzyme
1.14.14.84
Pathway
rn00902  Monoterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.84
     R09923  (-)-Linalool + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> (6E)-8-Hydroxylinalool + [Oxidized NADPH---hemoprotein reductase] + H2O
IUBMB reaction hierarchy [BR:br08202]
 1. Oxidoreductase reactions
  1.14.14.84
   R04366  Linalool <=> (6E)-8-Hydroxylinalool
    R09923  (-)-Linalool <=> (6E)-8-Hydroxylinalool
Orthology
K05525  linalool 8-monooxygenase [EC:1.14.14.84]
K23810  (E)-8-carboxylinalool synthase [EC:1.14.14.-]
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