KEGG   REACTION: R10320
Entry
R10320                      Reaction                               
Name
8-O-methyldihydrosterigmatocystin,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (aflatoxin-B forming)
Definition
Dihydro-O-methylsterigmatocystin + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> Aflatoxin B2 + 2 [Oxidized NADPH---hemoprotein reductase] + H2O + Methanol + CO2
Equation
C03944 + 2 C03024 + 2 C00007 <=> C16753 + 2 C03161 + C00001 + C00132 + C00011
Reaction class
RC03113  C03944_C16753
Enzyme
1.14.14.117
Pathway
rn00254  Aflatoxin biosynthesis
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.117
     R10320  Dihydro-O-methylsterigmatocystin + 2 [Reduced NADPH---hemoprotein reductase] + 2 Oxygen <=> Aflatoxin B2 + 2 [Oxidized NADPH---hemoprotein reductase] + H2O + Methanol + CO2
Orthology
K17651  aflatoxin B synthase [EC:1.14.14.117]
Other DBs
RHEA: 35766
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