KEGG   REACTION: R10379
Entry
R10379                      Reaction                               
Definition
12-Demethyl-11,12-dehydropaspaline + 3 Oxygen + 3 NADPH + 3 H+ <=> Terpendole I + 3 NADP+ + 3 H2O
Equation
C20534 + 3 C00007 + 3 C00005 + 3 C00080 <=> C20543 + 3 C00006 + 3 C00001
Comment
cytochrome P450, LtmQ
multi-step reaction
Reaction class
RC00001  C00005_C00006
RC03144  C20534_C20543
Enzyme
1.14.13.-
Pathway
rn00403  Indole diterpene alkaloid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.-
     R10379  12-Demethyl-11,12-dehydropaspaline + 3 Oxygen + 3 NADPH + 3 H+ <=> Terpendole I + 3 NADP+ + 3 H2O
Orthology
K18393  cytochrome P450 monooxygenase [EC:1.14.13.-]
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