KEGG   REACTION: R10499
Entry
R10499                      Reaction                               
Name
L-phenylalanine:2-oxo-acid aminotransferase
Definition
L-Phenylalanine + 2-Oxo acid <=> Phenylpyruvate + L-Amino acid
Equation
C00079 + C00161 <=> C00166 + C00151
Reaction class
RC00006  C00079_C00166
RC00025  C00151_C00161
Enzyme
2.6.1.-
Pathway
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.-
     R10499  L-Phenylalanine + 2-Oxo acid <=> Phenylpyruvate + L-Amino acid
LinkDB

KEGG   REACTION: R10500
Entry
R10500                      Reaction                               
Name
acetyl-CoA:phenylpyruvate C-acetyltransferase (thioester-hydrolysing, carboxymethyl-forming)
Definition
Phenylpyruvate + Acetyl-CoA + H2O <=> 2-Benzylmalic acid + CoA
Equation
C00166 + C00024 + C00001 <=> C20653 + C00010
Reaction class
RC00004  C00010_C00024
RC00067  C00166_C20653
Enzyme
2.3.3.-
Pathway
rn00400  Phenylalanine, tyrosine and tryptophan biosynthesis
rn01100  Metabolic pathways
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.3  Acyl groups converted into alkyl groups on transfer
    2.3.3.-
     R10500  Phenylpyruvate + Acetyl-CoA + H2O <=> 2-Benzylmalic acid + CoA
Orthology
K17748  benzylmalate synthase [EC:2.3.3.-]
LinkDB

KEGG   REACTION: R10501
Entry
R10501                      Reaction                               
Name
2-benzylmalate hydro-lyase (3-benzylmalate-forming)
Definition
2-Benzylmalic acid <=> 3-Benzylmalic acid
Equation
C20653 <=> C20654
Comment
possibly two-step reaction (similar to ec 4.2.1.33, R03968+R04001)
Reaction class
RC00497  C20653_C20654
Enzyme
4.2.1.-
Pathway
rn00400  Phenylalanine, tyrosine and tryptophan biosynthesis
rn01100  Metabolic pathways
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 4. Lyase reactions
  4.2  Carbon-oxygen lyases
   4.2.1  Hydro-lyases
    4.2.1.-
     R10501  2-Benzylmalic acid <=> 3-Benzylmalic acid
Orthology
K17749  3-benzylmalate isomerase [EC:4.2.1.-]
LinkDB

KEGG   REACTION: R10502
Entry
R10502                      Reaction                               
Name
3-benzylmalate:NAD+ oxidoreductase (decarboxylating)
Definition
3-Benzylmalic acid + NAD+ <=> 2-Oxo-4-phenylbutyric acid + CO2 + NADH + H+
Equation
C20654 + C00003 <=> C20327 + C00011 + C00004 + C00080
Reaction class
RC00001  C00003_C00004
RC00114  C20327_C20654
Enzyme
1.1.1.-
Pathway
rn00400  Phenylalanine, tyrosine and tryptophan biosynthesis
rn01100  Metabolic pathways
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.-
     R10502  3-Benzylmalic acid + NAD+ <=> 2-Oxo-4-phenylbutyric acid + CO2 + NADH + H+
Orthology
K17750  3-benzylmalate dehydrogenase [EC:1.1.1.-]
LinkDB

KEGG   REACTION: R10503
Entry
R10503                      Reaction                               
Name
L-amino acid:2-oxo-4-phenylbutyric-acid aminotransferase
Definition
2-Oxo-4-phenylbutyric acid + L-Amino acid <=> L-Homophenylalanine + 2-Oxo acid
Equation
C20327 + C00151 <=> C17235 + C00161
Reaction class
RC00006  C17235_C20327
RC00025  C00151_C00161
Enzyme
2.6.1.-
Pathway
rn00400  Phenylalanine, tyrosine and tryptophan biosynthesis
rn01100  Metabolic pathways
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.6  Transferring nitrogenous groups
   2.6.1  Transaminases
    2.6.1.-
     R10503  2-Oxo-4-phenylbutyric acid + L-Amino acid <=> L-Homophenylalanine + 2-Oxo acid
LinkDB

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