KEGG   REACTION: R10796
Entry
R10796                      Reaction                               
Name
2-hydroxy-5-methyl-1-naphthoate,reduced ferredoxin:oxygen oxidoreductase (7-hydroxylating)
Definition
2-Hydroxy-5-methyl-1-naphthoate + 2 Reduced ferredoxin + 2 H+ + Oxygen <=> 2,7-Dihydroxy-5-methyl-1-naphthoate + 2 Oxidized ferredoxin + H2O
Equation
C20856 + 2 C00138 + 2 C00080 + C00007 <=> C20857 + 2 C00139 + C00001
Reaction class
RC00490  C20856_C20857
Enzyme
1.14.15.31
Pathway
rn01059  Biosynthesis of enediyne antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00830  Neocarzinostatin naphthoate moiety biosynthesis, malonyl-CoA => 2-hydroxy-5-methyl-1-naphthoate => 2-hydroxy-7-methoxy-5-methyl-1-naphthoyl-CoA
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.31
     R10796  2-Hydroxy-5-methyl-1-naphthoate + 2 Reduced ferredoxin + 2 H+ + Oxygen <=> 2,7-Dihydroxy-5-methyl-1-naphthoate + 2 Oxidized ferredoxin + H2O
Orthology
K20420  2-hydroxy-5-methyl-1-naphthoate 7-hydroxylase [EC:1.14.15.31]
Other DBs
RHEA: 42831
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