KEGG   REACTION: R10878
Entry
R10878                      Reaction                               
Name
mycinamicin-V,NADPH:oxygen oxidoreductase (12,13-epoxidizing)
Definition
Mycinamicin V + NADPH + Oxygen + H+ <=> Mycinamicin II + NADP+ + H2O
Equation
C18847 + C00005 + C00007 + C00080 <=> C15680 + C00006 + C00001
Reaction class
RC00001  C00005_C00006
RC03294  C15680_C18847
Enzyme
1.14.13.-
Pathway
rn00522  Biosynthesis of 12-, 14- and 16-membered macrolides
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00934  Mycinamicin biosynthesis, malonyl-CoA + methylmalonyl-CoA => protomycinolide IV => mycinamicin II
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.13  With NADH or NADPH as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.13.-
     R10878  Mycinamicin V + NADPH + Oxygen + H+ <=> Mycinamicin II + NADP+ + H2O
Orthology
K24390  mycinamicin IV hydroxylase/epoxidase [EC:1.14.-.-]
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