KEGG   REACTION: R11358
Entry
R11358                      Reaction                               
Name
cholest-4-en-3-one,reduced-[2Fe-2S]-ferredoxin:oxygen oxidoreductase [(25R)-26-hydroxycholest-4-en-3-one forming]
Definition
Cholest-4-en-3-one + 2 Reduced [2Fe-2S] ferredoxin + Oxygen <=> (25R)-26-Hydroxycholest-4-en-3-one + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Equation
Comment
the first step of three-step reaction (see R11361, R11358+R11359+R11360)
Reaction class
RC01216  C00599_C21303
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.28
     R11358  Cholest-4-en-3-one + 2 Reduced [2Fe-2S] ferredoxin + Oxygen <=> (25R)-26-Hydroxycholest-4-en-3-one + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Orthology
K16046  cholest-4-en-3-one 26-monooxygenase [EC:1.14.15.28]
Other DBs
RHEA: 43915
LinkDB

KEGG   REACTION: R11359
Entry
R11359                      Reaction                               
Name
(25R)-26-hydroxycholest-4-en-3-one,reduced-[2Fe-2S]-ferredoxin:oxygen oxidoreductase [(25R)-26-oxocholest-4-en-3-one forming]
Definition
(25R)-26-Hydroxycholest-4-en-3-one + 2 Reduced [2Fe-2S] ferredoxin + Oxygen <=> (25R)-26-Oxocholest-4-en-3-one + 2 Oxidized [2Fe-2S] ferredoxin + 2 H2O
Equation
C21303 + 2 C22150 + C00007 <=> C21305 + 2 C22151 + 2 C00001
Comment
the second step of three-step reaction (see R11361, R11358+R11359+R11360)
Reaction class
RC00099  C21303_C21305
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.28
     R11359  (25R)-26-Hydroxycholest-4-en-3-one + 2 Reduced [2Fe-2S] ferredoxin + Oxygen <=> (25R)-26-Oxocholest-4-en-3-one + 2 Oxidized [2Fe-2S] ferredoxin + 2 H2O
Orthology
K16046  cholest-4-en-3-one 26-monooxygenase [EC:1.14.15.28]
Other DBs
RHEA: 43919
LinkDB

KEGG   REACTION: R11360
Entry
R11360                      Reaction                               
Name
(25R)-26-oxocholest-4-en-3-one,reduced-[2Fe-2S]-ferredoxin:oxygen oxidoreductase [(25R)-3-oxocholest-4-en-26-oate forming]
Definition
(25R)-26-Oxocholest-4-en-3-one + 2 Reduced [2Fe-2S] ferredoxin + Oxygen <=> (25R)-3-Oxocholest-4-en-26-oate + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Equation
Comment
the last step of three-step reaction (see R11361, R11358+R11359+R11360)
Reaction class
RC00242  C20839_C21305
Enzyme
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.28
     R11360  (25R)-26-Oxocholest-4-en-3-one + 2 Reduced [2Fe-2S] ferredoxin + Oxygen <=> (25R)-3-Oxocholest-4-en-26-oate + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Orthology
K16046  cholest-4-en-3-one 26-monooxygenase [EC:1.14.15.28]
Other DBs
RHEA: 43923
LinkDB

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