KEGG   REACTION: R11412
Entry
R11412                      Reaction                               
Definition
Acetyl-CoA + 3 Malonyl-CoA + Acyl-carrier protein <=> Orsellinate-[acp] + 4 CoA + 3 CO2 + H2O
Equation
C00024 + 3 C00083 + C00229 <=> C21343 + 4 C00010 + 3 C00011 + C00001
Enzyme
2.3.1.-
Pathway
rn01059  Biosynthesis of enediyne antibiotics
rn01100  Metabolic pathways
rn01110  Biosynthesis of secondary metabolites
Module
M00833  Calicheamicin biosynthesis, calicheamicinone => calicheamicin
M00834  Calicheamicin orsellinate moiety biosynthesis, malonyl-CoA => orsellinate-ACP => 5-iodo-2,3-dimethoxyorsellinate-ACP
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.3  Acyltransferases
   2.3.1  Transferring groups other than aminoacyl groups
    2.3.1.-
     R11412  Acetyl-CoA + 3 Malonyl-CoA + Acyl-carrier protein <=> Orsellinate-[acp] + 4 CoA + 3 CO2 + H2O
Orthology
K21254  orsellinic acid synthase [EC:2.3.1.-]
LinkDB

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