KEGG   REACTION: R11981
Entry
R11981                      Reaction                               
Name
ent-cassa-12,15-diene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (ent-3beta-hydroxycassa-12,15-dien-2-one forming)
Definition
ent-Cassa-12,15-diene + 3 [Reduced NADPH---hemoprotein reductase] + 3 Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + 3 [Oxidized NADPH---hemoprotein reductase] + 4 H2O
Equation
C18226 + 3 C03024 + 3 C00007 <=> C21826 + 3 C03161 + 4 C00001
Comment
three-step reaction (see R11982+R11983+R11984, R11982+R11985+R11986)
Reaction class
RC03513  C18226_C21826
Enzyme
1.14.14.69
Pathway
rn00904  Diterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11981  ent-Cassa-12,15-diene + 3 [Reduced NADPH---hemoprotein reductase] + 3 Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + 3 [Oxidized NADPH---hemoprotein reductase] + 4 H2O
Orthology
K21291  ent-cassadiene hydroxylase [EC:1.14.14.69]
Other DBs
RHEA: 55483
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