KEGG   REACTION: R12094
Entry
R12094                      Reaction                               
Definition
Chanoclavine-I aldehyde + H+ <=> 6,8-Dimethyl-6,7,8,9-tetradehydroergoline + H2O
Equation
C20379 + C00080 <=> C20457 + C00001
Comment
spontaneous
Pathway
rn00901  Indole alkaloid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Reference
1  [PMID:21494745]
  Authors
Matuschek M, Wallwey C, Xie X, Li SM
  Title
New insights into ergot alkaloid biosynthesis in Claviceps purpurea: an agroclavine synthase EasG catalyses, via a non-enzymatic adduct with reduced glutathione, the conversion of chanoclavine-I aldehyde to agroclavine.
  Journal
Org Biomol Chem 9:4328-35 (2011)
DOI:10.1039/c0ob01215g
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