KEGG   REACTION: R12301
Entry
R12301                      Reaction                               
Definition
o-Methoxyphenol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Catechol + [Oxidized NADPH---hemoprotein reductase] + Formaldehyde + H2O
Equation
C01502 + C03024 + C00007 <=> C00090 + C03161 + C00067 + C00001
Comment
guaiacol O-demethylase
Reaction class
RC00392  C00090_C01502
Enzyme
1.14.14.-
Pathway
rn00627  Aminobenzoate degradation
rn01120  Microbial metabolism in diverse environments
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.-
     R12301  o-Methoxyphenol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> Catechol + [Oxidized NADPH---hemoprotein reductase] + Formaldehyde + H2O
Orthology
K23526  aromatic O-demethylase, cytochrome P450 subunit [EC:1.14.14.-]
K23527  aromatic O-demethylase, reductase subunit [EC:1.6.2.-]
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