KEGG   REACTION: R12567
Entry
R12567                      Reaction                               
Definition
2-Acetamido-4-(D-alanylamino)-2,4,6-trideoxy-D-mannopyranose + Phosphoenolpyruvate + H2O <=> 5-N-Acetyl-7-N-(D-alanyl)-legionaminic acid + Orthophosphate
Equation
C22249 + C00074 + C00001 <=> C22250 + C00009
Comment
transferase
Reaction class
RC00159  C22249_C22250
Enzyme
2.5.1.-
Pathway
rn00541  Biosynthesis of various nucleotide sugars
rn01100  Metabolic pathways
rn01250  Biosynthesis of nucleotide sugars
Module
M01012  CMP-Leg5Ac7Ala biosynthesis, UDP-GlcNAc => CMP-Leg5Ac7Ala
Brite
Enzymatic reactions [BR:br08201]
 2. Transferase reactions
  2.5  Transferring alkyl or aryl groups, other than methyl groups
   2.5.1  Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)
    2.5.1.-
     R12567  2-Acetamido-4-(D-alanylamino)-2,4,6-trideoxy-D-mannopyranose + Phosphoenolpyruvate + H2O <=> 5-N-Acetyl-7-N-(D-alanyl)-legionaminic acid + Orthophosphate
Orthology
K24306  2-acetamido-4-(D-alanylamino)-2,4,6-trideoxy-D-mannopyranose transferase
Reference
1  [PMID:20510395]
  Authors
Li X, Perepelov AV, Wang Q, Senchenkova SN, Liu B, Shevelev SD, Guo X, Shashkov AS, Chen W, Wang L, Knirel YA
  Title
Structural and genetic characterization of the O-antigen of Escherichia coli O161 containing a derivative of a higher acidic diamino sugar, legionaminic acid.
  Journal
Carbohydr Res 345:1581-7 (2010)
DOI:10.1016/j.carres.2010.04.008
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