KEGG   MODULE: M00952
Entry
M00952            Pathway   Module                                 
Name
Benzoxazinoid biosynthesis, indoleglycerol phosphate => DIMBOA-glucoside
Definition
K13222 K13223 K13224 K13225 K13226 K13227 K13229 K13230
Diagram
M00952

Orthology
K13222  
BX1; indole-3-glycerol-phosphate lyase [EC:4.1.2.8] [RN:R02340]
K13223  
BX2; indole-2-monooxygenase [EC:1.14.14.153] [RN:R07403]
K13224  
BX3; indolin-2-one monooxygenase [EC:1.14.14.157] [RN:R07421]
K13225  
BX4; 3-hydroxyindolin-2-one monooxygenase [EC:1.14.14.109] [RN:R07422]
K13226  
BX5; 2-hydroxy-1,4-benzoxazin-3-one monooxygenase [EC:1.14.14.110] [RN:R07423]
K13227  
BX8_9; UDP-glucosyltransferase BX8/BX9 [EC:2.4.1.202] [RN:R07426]
K13229  
BX6; 2,4-dihydroxy-1,4-benzoxazin-3-one-glucoside dioxygenase [EC:1.14.11.59] [RN:R08972]
K13230  
BX7; 2,4,7-trihydroxy-1,4-benzoxazin-3-one-glucoside 7-O-methyltransferase [EC:2.1.1.241] [RN:R08973]
Class
Pathway modules; Biosynthesis of other secondary metabolites; Biosynthesis of phytochemical compounds
Pathway
map00999  Biosynthesis of various plant secondary metabolites
map01100  Metabolic pathways
map01110  Biosynthesis of secondary metabolites
Reaction
Compound
C03506  Indoleglycerol phosphate
C00463  Indole
C12312  Indolin-2-one
C11130  3-Hydroxyindolin-2-one
C15769  HBOA
C15770  DIBOA
C15772  DIBOA-glucoside
C18062  TRIBOA-glucoside
C04831  DIMBOA-glucoside
Reference
  Authors
Frey M, Schullehner K, Dick R, Fiesselmann A, Gierl A
  Title
Benzoxazinoid biosynthesis, a model for evolution of secondary metabolic pathways in plants.
  Journal
Phytochemistry 70:1645-51 (2009)
DOI:10.1016/j.phytochem.2009.05.012
Reference
  Authors
Jonczyk R, Schmidt H, Osterrieder A, Fiesselmann A, Schullehner K, Haslbeck M, Sicker D, Hofmann D, Yalpani N, Simmons C, Frey M, Gierl A
  Title
Elucidation of the final reactions of DIMBOA-glucoside biosynthesis in maize: characterization of Bx6 and Bx7.
  Journal
Plant Physiol 146:1053-63 (2008)
DOI:10.1104/pp.107.111237
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