KEGG   REACTION: R05185
Entry
R05185                      Reaction                               
Name
reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
Definition
16 ATP + Nitrogen + 8 Reduced ferredoxin + 8 H+ + 16 H2O <=> 16 Orthophosphate + 16 ADP + 8 Oxidized ferredoxin + 2 Ammonia + Hydrogen
Equation
16 C00002 + C00697 + 8 C00138 + 8 C00080 + 16 C00001 <=> 16 C00009 + 16 C00008 + 8 C00139 + 2 C00014 + C00282
Comment
multi-step reaction (see R00002+R00067+R00153+R02802+R04782)
Reaction class
RC00002  C00002_C00008
RC02891  C00014_C00697
Enzyme
1.18.6.1
Pathway
rn00910  Nitrogen metabolism
rn01100  Metabolic pathways
rn01120  Microbial metabolism in diverse environments
Module
M00175  Nitrogen fixation, nitrogen => ammonia
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.18  Acting on iron-sulfur proteins as donors
   1.18.6  With dinitrogen as acceptor
    1.18.6.1
     R05185  16 ATP + Nitrogen + 8 Reduced ferredoxin + 8 H+ + 16 H2O <=> 16 Orthophosphate + 16 ADP + 8 Oxidized ferredoxin + 2 Ammonia + Hydrogen
Orthology
K00531  nitrogenase delta subunit [EC:1.18.6.1]
K02586  nitrogenase molybdenum-iron protein alpha chain [EC:1.18.6.1]
K02588  nitrogenase iron protein NifH
K02591  nitrogenase molybdenum-iron protein beta chain [EC:1.18.6.1]
Other DBs
RHEA: 21451
LinkDB

KEGG   REACTION: R00002
Entry
R00002                      Reaction                               
Name
reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
Definition
16 ATP + 16 H2O + 8 Reduced ferredoxin <=> 8 e- + 16 Orthophosphate + 16 ADP + 8 Oxidized ferredoxin
Equation
16 C00002 + 16 C00001 + 8 C00138 <=> 8 C05359 + 16 C00009 + 16 C00008 + 8 C00139
Comment
a part of multi-step reaction (see R05185, R00002+R00067+R00153+R02802+R04782)
Reaction class
RC00002  C00002_C00008
Enzyme
1.18.6.1
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.18  Acting on iron-sulfur proteins as donors
   1.18.6  With dinitrogen as acceptor
    1.18.6.1
     R00002  16 ATP + 16 H2O + 8 Reduced ferredoxin <=> 8 e- + 16 Orthophosphate + 16 ADP + 8 Oxidized ferredoxin
LinkDB

KEGG   REACTION: R00067
Entry
R00067                      Reaction                               
Name
reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
Definition
2 e- + 2 H+ <=> Hydrogen
Equation
2 C05359 + 2 C00080 <=> C00282
Comment
a part of multi-step reaction (see R05185, R00002+R00067+R00153+R02802+R04782)
Enzyme
1.18.6.1
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.18  Acting on iron-sulfur proteins as donors
   1.18.6  With dinitrogen as acceptor
    1.18.6.1
     R00067  2 e- + 2 H+ <=> Hydrogen
LinkDB

KEGG   REACTION: R00153
Entry
R00153                      Reaction                               
Name
reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
Definition
Hydrazine + 2 e- + 2 H+ <=> 2 Ammonia
Equation
C05361 + 2 C05359 + 2 C00080 <=> 2 C00014
Comment
a part of multi-step reaction (see R05185, R00002+R00067+R00153+R02802+R04782)
Enzyme
1.18.6.1
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.18  Acting on iron-sulfur proteins as donors
   1.18.6  With dinitrogen as acceptor
    1.18.6.1
     R00153  Hydrazine + 2 e- + 2 H+ <=> 2 Ammonia
LinkDB

KEGG   REACTION: R02802
Entry
R02802                      Reaction                               
Name
reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
Definition
Nitrogen + 2 e- + 2 H+ <=> Diimine
Equation
C00697 + 2 C05359 + 2 C00080 <=> C05360
Comment
a part of multi-step reaction (see R05185, R00002+R00067+R00153+R02802+R04782)
Enzyme
1.18.6.1
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.18  Acting on iron-sulfur proteins as donors
   1.18.6  With dinitrogen as acceptor
    1.18.6.1
     R02802  Nitrogen + 2 e- + 2 H+ <=> Diimine
LinkDB

KEGG   REACTION: R04782
Entry
R04782                      Reaction                               
Name
reduced ferredoxin:dinitrogen oxidoreductase (ATP-hydrolysing)
Definition
Diimine + 2 e- + 2 H+ <=> Hydrazine
Equation
C05360 + 2 C05359 + 2 C00080 <=> C05361
Comment
a part of multi-step reaction (see R05185, R00002+R00067+R00153+R02802+R04782)
Enzyme
1.18.6.1
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.18  Acting on iron-sulfur proteins as donors
   1.18.6  With dinitrogen as acceptor
    1.18.6.1
     R04782  Diimine + 2 e- + 2 H+ <=> Hydrazine
LinkDB

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