KEGG   REACTION: R08621
Entry
R08621                      Reaction                               
Name
3-(2'-methylthio)ethylmalate:NAD+ oxidoreductase (decarboxylating)
Definition
3-(2'-Methylthio)ethylmalic acid + NAD+ <=> 2-Oxo-5-methylthiopentanoic acid + CO2 + NADH + H+
Equation
C17212 + C00003 <=> C17211 + C00011 + C00004 + C00080
Comment
two-step reaction (similar to R10052, R04426+R01652)
Reaction class
RC00114  C17211_C17212
Enzyme
1.1.1.-
Pathway
rn00966  Glucosinolate biosynthesis
rn01110  Biosynthesis of secondary metabolites
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.-
     R08621  3-(2'-Methylthio)ethylmalic acid + NAD+ <=> 2-Oxo-5-methylthiopentanoic acid + CO2 + NADH + H+
Orthology
K21360  3-isopropylmalate/methylthioalkylmalate dehydrogenase [EC:1.1.1.85 1.1.1.-]
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