KEGG   REACTION: R08642
Entry
R08642                      Reaction                               
Name
3-(6'-methylthio)hexylmalate:NAD+ oxidoreductase (decarboxylating)
Definition
3-(6'-Methylthio)hexylmalic acid + NAD+ <=> 2-Oxo-9-methylthiononanoic acid + CO2 + NADH + H+
Equation
C17227 + C00003 <=> C17228 + C00011 + C00004 + C00080
Comment
two-step reaction (similar to R10052, R04426+R01652)
Reaction class
RC00114  C17227_C17228
Enzyme
1.1.1.-
Pathway
rn00966  Glucosinolate biosynthesis
rn01210  2-Oxocarboxylic acid metabolism
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.1  Acting on the CH-OH group of donors
   1.1.1  With NAD+ or NADP+ as acceptor
    1.1.1.-
     R08642  3-(6'-Methylthio)hexylmalic acid + NAD+ <=> 2-Oxo-9-methylthiononanoic acid + CO2 + NADH + H+
Orthology
K21360  3-isopropylmalate/methylthioalkylmalate dehydrogenase [EC:1.1.1.85 1.1.1.-]
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