KEGG   REACTION: R10072
Entry
R10072                      Reaction                               
Name
(+)-epi-isozizaene,reduced-ferredoxin:oxygen oxidoreductase (5-hydroxylating)
Definition
(+)-epi-Isozizaene + 4 Reduced [2Fe-2S] ferredoxin + 4 H+ + 2 Oxygen <=> Albaflavenone + 4 Oxidized [2Fe-2S] ferredoxin + 3 H2O
Equation
C16269 + 4 C22150 + 4 C00080 + 2 C00007 <=> C17954 + 4 C22151 + 3 C00001
Comment
two-step reaction (see R08851+R08852, R08853+R08854)
Reaction class
RC01900  C16269_C17954
Enzyme
1.14.15.39
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.39
     R10072  (+)-epi-Isozizaene + 4 Reduced [2Fe-2S] ferredoxin + 4 H+ + 2 Oxygen <=> Albaflavenone + 4 Oxidized [2Fe-2S] ferredoxin + 3 H2O
Orthology
K12645  epi-isozizaene 5-monooxygenase / beta-farnesene synthase [EC:1.14.15.39 4.2.3.47]
Other DBs
RHEA: 32442
LinkDB

KEGG   REACTION: R08851
Entry
R08851                      Reaction                               
Name
(+)-epi-isozizaene,reduced-ferredoxin:oxygen oxidoreductase (5S-hydroxylating)
Definition
(+)-epi-Isozizaene + 2 Reduced [2Fe-2S] ferredoxin + 2 H+ + Oxygen <=> (5S)-Albaflavenol + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Equation
C16269 + 2 C22150 + 2 C00080 + C00007 <=> C17953 + 2 C22151 + C00001
Comment
the first step of two-step reaction (see R10072, R08851+R08852)
(R)-form (see R08853+R08854)
Reaction class
RC00723  C16269_C17953
Enzyme
1.14.15.39
Pathway
rn00909  Sesquiterpenoid and triterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.39
     R08851  (+)-epi-Isozizaene + 2 Reduced [2Fe-2S] ferredoxin + 2 H+ + Oxygen <=> (5S)-Albaflavenol + 2 Oxidized [2Fe-2S] ferredoxin + H2O
Orthology
K12645  epi-isozizaene 5-monooxygenase / beta-farnesene synthase [EC:1.14.15.39 4.2.3.47]
Other DBs
RHEA: 25979
LinkDB

KEGG   REACTION: R08852
Entry
R08852                      Reaction                               
Name
(5S)-albaflavenol,reduced-ferredoxin:oxygen oxidoreductase
Definition
(5S)-Albaflavenol + 2 Reduced [2Fe-2S] ferredoxin + 2 H+ + Oxygen <=> Albaflavenone + 2 Oxidized [2Fe-2S] ferredoxin + 2 H2O
Equation
C17953 + 2 C22150 + 2 C00080 + C00007 <=> C17954 + 2 C22151 + 2 C00001
Comment
the second step of two-step reaction (see R10072, R08851+R08852)
(R)-form (see R08853+R08854)
Reaction class
RC00850  C17953_C17954
Enzyme
1.14.15.39
Pathway
rn00909  Sesquiterpenoid and triterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.15  With reduced iron-sulfur protein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.15.39
     R08852  (5S)-Albaflavenol + 2 Reduced [2Fe-2S] ferredoxin + 2 H+ + Oxygen <=> Albaflavenone + 2 Oxidized [2Fe-2S] ferredoxin + 2 H2O
Orthology
K12645  epi-isozizaene 5-monooxygenase / beta-farnesene synthase [EC:1.14.15.39 4.2.3.47]
Other DBs
RHEA: 25983
LinkDB

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