KEGG   REACTION: R11650
Entry
R11650                      Reaction                               
Name
(E)-omega-(methylthio)alkananaldoxime,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (N-hydroxylating)
Definition
omega-(Methylthio)-(E)-alkanal oxime + [Reduced NADPH---hemoprotein reductase] + Glutathione + Oxygen <=> (E)-1-(Glutathione-S-yl)-omega-(methylthio)alkylhydroximate + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C21535 + C03024 + C00051 + C00007 <=> C21539 + C03161 + 2 C00001
Comment
two-step reaction (see R11651+R11652)
Reaction class
RC03482  C21535_C21539
Enzyme
1.14.14.43
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.43
     R11650  omega-(Methylthio)-(E)-alkanal oxime + [Reduced NADPH---hemoprotein reductase] + Glutathione + Oxygen <=> (E)-1-(Glutathione-S-yl)-omega-(methylthio)alkylhydroximate + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 51995
LinkDB

KEGG   REACTION: R11651
Entry
R11651                      Reaction                               
Definition
omega-(Methylthio)-(E)-alkanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 1-aci-Nitro-omega-(methylthio)alkane + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C21535 + C03024 + C00007 <=> C21538 + C03161 + C00001
Comment
the first step of two-step reaction (see R11650, R11651+R11652)
Reaction class
RC02452  C21535_C21538
Enzyme
1.14.14.43
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.43
     R11651  omega-(Methylthio)-(E)-alkanal oxime + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> 1-aci-Nitro-omega-(methylthio)alkane + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 51999
LinkDB

KEGG   REACTION: R11652
Entry
R11652                      Reaction                               
Definition
1-aci-Nitro-omega-(methylthio)alkane + Glutathione <=> (E)-1-(Glutathione-S-yl)-omega-(methylthio)alkylhydroximate + H2O
Equation
C21538 + C00051 <=> C21539 + C00001
Comment
the second step of two-step reaction (see R11650, R11651+R11652)
Reaction class
RC02367  C21538_C21539
Enzyme
1.14.14.43
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.43
     R11652  1-aci-Nitro-omega-(methylthio)alkane + Glutathione <=> (E)-1-(Glutathione-S-yl)-omega-(methylthio)alkylhydroximate + H2O
Other DBs
RHEA: 52003
LinkDB

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