KEGG   REACTION: R11981
Entry
R11981                      Reaction                               
Name
ent-cassa-12,15-diene,[reduced NADPH---hemoprotein reductase]:oxygen oxidoreductase (ent-3beta-hydroxycassa-12,15-dien-2-one forming)
Definition
ent-Cassa-12,15-diene + 3 [Reduced NADPH---hemoprotein reductase] + 3 Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + 3 [Oxidized NADPH---hemoprotein reductase] + 4 H2O
Equation
C18226 + 3 C03024 + 3 C00007 <=> C21826 + 3 C03161 + 4 C00001
Comment
three-step reaction (see R11982+R11983+R11984, R11982+R11985+R11986)
Reaction class
RC03513  C18226_C21826
Enzyme
1.14.14.69
Pathway
rn00904  Diterpenoid biosynthesis
rn01110  Biosynthesis of secondary metabolites
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11981  ent-Cassa-12,15-diene + 3 [Reduced NADPH---hemoprotein reductase] + 3 Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + 3 [Oxidized NADPH---hemoprotein reductase] + 4 H2O
Orthology
K21291  ent-cassadiene hydroxylase [EC:1.14.14.69]
Other DBs
RHEA: 55483
LinkDB

KEGG   REACTION: R11982
Entry
R11982                      Reaction                               
Definition
ent-Cassa-12,15-diene + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-dien-2beta-ol + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C18226 + C03024 + C00007 <=> C21827 + C03161 + C00001
Comment
the first step of three-step reaction (see R11981, R11982+R11983+R11984, R11982+R11985+R11986)
Reaction class
RC00478  C18226_C21827
Enzyme
1.14.14.69
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11982  ent-Cassa-12,15-diene + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-dien-2beta-ol + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 55487
LinkDB

KEGG   REACTION: R11983
Entry
R11983                      Reaction                               
Definition
ent-Cassa-12,15-dien-2beta-ol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-dien-2-one + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C21827 + C03024 + C00007 <=> C21828 + C03161 + 2 C00001
Comment
the second step of three-step reaction (see R11981, R11982+R11983+R11984)
Reaction class
RC00144  C21827_C21828
Enzyme
1.14.14.69
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11983  ent-Cassa-12,15-dien-2beta-ol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-dien-2-one + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 55491
LinkDB

KEGG   REACTION: R11984
Entry
R11984                      Reaction                               
Definition
ent-Cassa-12,15-dien-2-one + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C21828 + C03024 + C00007 <=> C21826 + C03161 + C00001
Comment
the last step of three-step reaction (see R11981, R11982+R11983+R11984)
Reaction class
RC03493  C21826_C21828
Enzyme
1.14.14.69
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11984  ent-Cassa-12,15-dien-2-one + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 55495
LinkDB

KEGG   REACTION: R11982
Entry
R11982                      Reaction                               
Definition
ent-Cassa-12,15-diene + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-dien-2beta-ol + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C18226 + C03024 + C00007 <=> C21827 + C03161 + C00001
Comment
the first step of three-step reaction (see R11981, R11982+R11983+R11984, R11982+R11985+R11986)
Reaction class
RC00478  C18226_C21827
Enzyme
1.14.14.69
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11982  ent-Cassa-12,15-diene + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-dien-2beta-ol + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 55487
LinkDB

KEGG   REACTION: R11985
Entry
R11985                      Reaction                               
Definition
ent-Cassa-12,15-dien-2beta-ol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-diene-2beta,3beta-diol + [Oxidized NADPH---hemoprotein reductase] + H2O
Equation
C21827 + C03024 + C00007 <=> C21829 + C03161 + C00001
Comment
the second step of three-step reaction (see R11981, R11982+R11985+R11986)
Reaction class
RC01993  C21827_C21829
Enzyme
1.14.14.69
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11985  ent-Cassa-12,15-dien-2beta-ol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-Cassa-12,15-diene-2beta,3beta-diol + [Oxidized NADPH---hemoprotein reductase] + H2O
Other DBs
RHEA: 55499
LinkDB

KEGG   REACTION: R11986
Entry
R11986                      Reaction                               
Definition
ent-Cassa-12,15-diene-2beta,3beta-diol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Equation
C21829 + C03024 + C00007 <=> C21826 + C03161 + 2 C00001
Comment
the last step of three-step reaction (see R11981, R11982+R11985+R11986)
Reaction class
RC00154  C21826_C21829
Enzyme
1.14.14.69
Brite
Enzymatic reactions [BR:br08201]
 1. Oxidoreductase reactions
  1.14  Acting on paired donors, with incorporation or reduction of molecular oxygen
   1.14.14  With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor
    1.14.14.69
     R11986  ent-Cassa-12,15-diene-2beta,3beta-diol + [Reduced NADPH---hemoprotein reductase] + Oxygen <=> ent-3beta-Hydroxycassa-12,15-dien-2-one + [Oxidized NADPH---hemoprotein reductase] + 2 H2O
Other DBs
RHEA: 55503
LinkDB

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